12 Metallurgy for inspectors · 12 min
Why steel cracks after you go home
Hydrogen + hardness + stress. Carbon equivalent tells you how mean the HAZ can get.
Inspectors are not metallurgists. You still need the story, because the WPS preheat, the rod oven, and the delay-before-inspection rule all come from it.
- Carbon equivalent (CE): a weighted sum of C, Mn, Cr, Mo, V, Ni, Cu. Higher CE → more hardenability → harder HAZ if you cool fast → more hydrogen-crack risk. Thick sections cool faster at the core than you think.
- Hydrogen cracking (cold crack, delayed crack): appears at room temperature, often in the HAZ, sometimes hours later. Needs hydrogen, a susceptible microstructure, and stress. Kill any one of the three.
- Preheat and interpass: slow the cool, let hydrogen diffuse out as atomic hydrogen while the metal is still warm.
- Low-hydrogen consumables and dry joint surfaces: starve the hydrogen.
- Hot cracks (solidification): in the weld metal as it freezes — crater cracks, centreline cracks, high sulphur/phosphorus, deep narrow beads. Different animal from hydrogen cracks.
- Lamellar tearing: terraced cracking in the base metal under a T-joint, from inclusions in the rolling plane plus through-thickness strain. Material and joint design problem.
- Toughness / CVN: ability to absorb energy at temperature. Required on many bridges and seismic members. A pretty weld with no Charpy is still the wrong weld if the WPS demanded it.
IIW CE ≈ C + Mn/6 + (Cr+Mo+V)/5 + (Ni+Cu)/15
Know that it exists and what it is for. Do not pretend this is the only CE formula — your WPS and W59 edition name the one that matters.