12 Metallurgy for inspectors · 12 min

Why steel cracks after you go home

Hydrogen + hardness + stress. Carbon equivalent tells you how mean the HAZ can get.

Inspectors are not metallurgists. You still need the story, because the WPS preheat, the rod oven, and the delay-before-inspection rule all come from it.

  • Carbon equivalent (CE): a weighted sum of C, Mn, Cr, Mo, V, Ni, Cu. Higher CE → more hardenability → harder HAZ if you cool fast → more hydrogen-crack risk. Thick sections cool faster at the core than you think.
  • Hydrogen cracking (cold crack, delayed crack): appears at room temperature, often in the HAZ, sometimes hours later. Needs hydrogen, a susceptible microstructure, and stress. Kill any one of the three.
  • Preheat and interpass: slow the cool, let hydrogen diffuse out as atomic hydrogen while the metal is still warm.
  • Low-hydrogen consumables and dry joint surfaces: starve the hydrogen.
  • Hot cracks (solidification): in the weld metal as it freezes — crater cracks, centreline cracks, high sulphur/phosphorus, deep narrow beads. Different animal from hydrogen cracks.
  • Lamellar tearing: terraced cracking in the base metal under a T-joint, from inclusions in the rolling plane plus through-thickness strain. Material and joint design problem.
  • Toughness / CVN: ability to absorb energy at temperature. Required on many bridges and seismic members. A pretty weld with no Charpy is still the wrong weld if the WPS demanded it.

IIW CE ≈ C + Mn/6 + (Cr+Mo+V)/5 + (Ni+Cu)/15

Know that it exists and what it is for. Do not pretend this is the only CE formula — your WPS and W59 edition name the one that matters.

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